The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jun. 07, 2016

Filed:

Sep. 20, 2013
Applicants:

Ut-battelle, Llc, Oak Ridge, TN (US);

University of Tennessee Research Foundation, Knoxville, TN (US);

Inventors:

Yatsandra Oyola, Paducah, KY (US);

Chengcheng Tian, Shanghai, CN;

John Christopher Bauer, Paducah, KY (US);

Sheng Dai, Knoxville, TN (US);

Assignees:

UT-BATTELLE, LLC, Oak Ridge, TN (US);

UNIVERSITY OF TENNESSEE RESEARCH FOUNDATION, Knoxville, TN (US);

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C07D 307/48 (2006.01);
U.S. Cl.
CPC ...
C07D 307/48 (2013.01);
Abstract

An acid-functionalized polyolefin material that can be used as an acid catalyst in a wide range of acid-promoted chemical reactions, wherein the acid-functionalized polyolefin material includes a polyolefin backbone on which acid groups are appended. Also described is a method for the preparation of the acid catalyst in which a precursor polyolefin is subjected to ionizing radiation (e.g., electron beam irradiation) of sufficient power and the irradiated precursor polyolefin reacted with at least one vinyl monomer having an acid group thereon. Further described is a method for conducting an acid-promoted chemical reaction, wherein an acid-reactive organic precursor is contacted in liquid form with a solid heterogeneous acid catalyst comprising a polyolefin backbone of at least 1 micron in one dimension and having carboxylic acid groups and either sulfonic acid or phosphonic acid groups appended thereto.


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