The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
May. 31, 2016

Filed:

Jan. 02, 2014
Applicant:

Uchicago Argonne, Llc, Chicago, IL (US);

Inventors:

Beihai Ma, Naperville, IL (US);

Manoj Narayanan, Woodridge, IL (US);

Uthamalingam Balachandran, Willowbrook, IL (US);

Sheng Chao, Woodridge, IL (US);

Shanshan Liu, Homer Glen, IL (US);

Assignee:

UCHICAGO ARGONNE, LLC, Chicago, IL (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
H01B 19/00 (2006.01); H01B 19/04 (2006.01); H01L 21/02 (2006.01); C04B 35/468 (2006.01); C04B 35/493 (2006.01); C04B 35/624 (2006.01); C04B 35/634 (2006.01); C23C 18/12 (2006.01); C23C 18/20 (2006.01);
U.S. Cl.
CPC ...
H01B 19/04 (2013.01); C04B 35/4682 (2013.01); C04B 35/493 (2013.01); C04B 35/624 (2013.01); C04B 35/634 (2013.01); C23C 18/1225 (2013.01); C23C 18/1254 (2013.01); C23C 18/1283 (2013.01); C23C 18/208 (2013.01); H01L 21/02118 (2013.01); H01L 21/02186 (2013.01); H01L 21/02189 (2013.01); H01L 21/02192 (2013.01); H01L 21/02194 (2013.01); H01L 21/02197 (2013.01); H01L 21/02282 (2013.01); C04B 2235/3213 (2013.01); C04B 2235/3227 (2013.01); C04B 2235/6562 (2013.01); Y10T 428/24975 (2015.01);
Abstract

The invention provides a process for forming crack-free dielectric films on a substrate. The process comprises the application of a dielectric precursor layer of a thickness from about 0.3 μm to about 1.0 μm to a substrate. The deposition is followed by low temperature heat pretreatment, prepyrolysis, pyrolysis and crystallization step for each layer. The deposition, heat pretreatment, prepyrolysis, pyrolysis and crystallization are repeated until the dielectric film forms an overall thickness of from about 1.5 μm to about 20.0 μm and providing a final crystallization treatment to form a thick dielectric film. The process provides a thick crack-free dielectric film on a substrate, the dielectric forming a dense thick crack-free dielectric having an overall dielectric thickness of from about 1.5 μm to about 20.0 μm.


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