The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
May. 31, 2016

Filed:

Apr. 27, 2015
Applicant:

Celanese International Corporation, Irving, TX (US);

Inventors:

Heiko Weiner, Pasadena, TX (US);

Zhenhua Zhou, Houston, TX (US);

Victor J. Johnson, Houston, TX (US);

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 29/149 (2006.01); B01J 23/00 (2006.01); B01J 23/835 (2006.01); B01J 23/89 (2006.01); B01J 37/00 (2006.01);
U.S. Cl.
CPC ...
C07C 29/149 (2013.01); B01J 23/00 (2013.01); B01J 23/002 (2013.01); B01J 23/835 (2013.01); B01J 23/8966 (2013.01); B01J 23/8973 (2013.01); B01J 23/8993 (2013.01); B01J 37/0009 (2013.01); Y02P 20/582 (2015.11);
Abstract

A process is disclosed for producing ethanol comprising contacting reactants comprising acetic acid and hydrogen in a reactor in the presence of a first catalyst in a first zone and a second catalyst in a second zone. The first catalyst is a mixed oxide comprising tin and at least one of cobalt or nickel. The second catalyst may be either: i) a supported Group VIII hydrogenation catalyst; ii) a copper-based catalyst; and iii) a secondary mixed oxide catalyst, wherein the secondary mixed oxide catalyst is different than the mixed oxide catalyst of the first zone.


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