The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
May. 24, 2016

Filed:

May. 07, 2009
Applicants:

Marek Matusz, Houston, TX (US);

Paul Michael Mcallister, Houston, TX (US);

Inventors:

Marek Matusz, Houston, TX (US);

Paul Michael McAllister, Houston, TX (US);

Assignee:

Shell Oil Company, Houston, TX (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07D 301/03 (2006.01); C07D 301/10 (2006.01);
U.S. Cl.
CPC ...
C07D 301/10 (2013.01); Y02P 20/142 (2015.11);
Abstract

A process is provided for the start-up of an ethylene epoxidation process comprising: (a) contacting a catalyst bed comprising a high selectivity epoxidation catalyst with a feed comprising ethylene, oxygen and an organic chloride for a period of time until an increase of at least 1×10mole-% of vinyl chloride (calculated as the moles of vinyl chloride relative to the total gas mixture), preferably 2×10mole-% of vinyl chloride is detected in a reactor outlet gas or a recycle gas loop; and (b) subsequently adjusting the quantity of organic chloride in the feed to a value sufficient to produce ethylene oxide at a substantially optimum selectivity.


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