The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Apr. 19, 2016

Filed:

Feb. 23, 2012
Applicants:

Jeffrey R. Long, Oakland, CA (US);

Christopher J. Chang, Berkeley, CA (US);

Hemamala I. Karunadasa, Palo Alto, CA (US);

Marcin Majda, Berkeley, CA (US);

Inventors:

Jeffrey R. Long, Oakland, CA (US);

Christopher J. Chang, Berkeley, CA (US);

Hemamala I. Karunadasa, Palo Alto, CA (US);

Marcin Majda, Berkeley, CA (US);

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07F 15/02 (2006.01); C07F 1/08 (2006.01); C25B 1/04 (2006.01); C07F 7/28 (2006.01); C07F 13/00 (2006.01); C07F 9/00 (2006.01); C07F 15/06 (2006.01); C07F 11/00 (2006.01); C25B 3/04 (2006.01); B01J 31/18 (2006.01); B01J 31/22 (2006.01);
U.S. Cl.
CPC ...
C25B 3/04 (2013.01); B01J 31/1815 (2013.01); B01J 31/226 (2013.01); C07F 11/005 (2013.01); B01J 2231/62 (2013.01); B01J 2531/0241 (2013.01); B01J 2531/16 (2013.01); B01J 2531/46 (2013.01); B01J 2531/56 (2013.01); B01J 2531/62 (2013.01); B01J 2531/64 (2013.01); B01J 2531/66 (2013.01); B01J 2531/72 (2013.01); B01J 2531/842 (2013.01); B01J 2531/845 (2013.01); B01J 2531/847 (2013.01);
Abstract

New metal persulfido compositions of matter are described. In one embodiment the metal is molybdenum and the metal persulfido complex mimics the structure and function of the triangular active edge site fragments of MoS, a material that is the current industry standard for petroleum hydro desulfurization, as well as a promising low-cost alternative to platinum for electrocatalytic hydrogen production. This molecular [(PY5W)MoS]containing catalyst is capable of generating hydrogen from acidic-buffered water or even seawater at very low overpotentials at a turnover frequency rate in excess of 500 moles Hper mole catalyst per second, with a turnover number (over a 20 hour period) of at least 19,000,000 moles Hper mole of catalyst.


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