The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Apr. 19, 2016

Filed:

Mar. 29, 2012
Applicants:

Van Gerardus Henricus Josephus Doremaele, Sittard, NL;

Martin Alexander Zuideveld, Maastricht, NL;

Victor Fidel Quiroga Norambuena, Lanaken, BE;

Philip Mountford, Oxford, GB;

Richard Scott, Gala Shiels, GB;

Inventors:
Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C08F 4/6592 (2006.01); C08F 4/642 (2006.01); C08F 4/643 (2006.01); C08F 210/16 (2006.01); C08F 4/76 (2006.01); C08F 10/02 (2006.01); C08F 4/52 (2006.01); B01J 31/14 (2006.01); B01J 31/16 (2006.01); B01J 31/18 (2006.01); B01J 31/22 (2006.01); C08F 4/659 (2006.01);
U.S. Cl.
CPC ...
C08F 4/76 (2013.01); C08F 4/52 (2013.01); C08F 4/6592 (2013.01); C08F 10/02 (2013.01); B01J 31/14 (2013.01); B01J 31/146 (2013.01); B01J 31/1608 (2013.01); B01J 31/1805 (2013.01); B01J 31/1825 (2013.01); B01J 31/2291 (2013.01); B01J 31/2295 (2013.01); B01J 2531/46 (2013.01); C08F 4/65908 (2013.01); C08F 4/65912 (2013.01); C08F 210/16 (2013.01); C08F 2420/03 (2013.01); Y02P 20/52 (2015.11);
Abstract

The invention relates to a catalyst system for the polymerization of olefins comprising a metal complex of formula CyLMD and an activating cocatalyst, wherein M is titanium, Cy is a cyclopentadienyl-type ligand, D is a diene, L is a guanidinate-containing ligand of the formula (I) wherein each A is independently selected from nitrogen or phosphorous and R, R, Rand Rare independently selected from the group consisting of hydrogen, hydrocarbyl, silyl and germyl residues, substituted or not with one or more halogen, amido, phosphido, alkoxy, or aryloxy radicals, and Cy is a mono- or polysubstituted cyclopentadienyl-type ligand, wherein the one or more substituents of Cy are selected from the group consisting of halogen, hydrocarbyl, silyl and germyl residues, optionally substituted with one or more halogen, amido, phosphido, alkoxy, or aryloxy residues. The invention further relates to a process for the preparation of a polymer comprising at least one aliphatic or aromatic hydrocarbyl Colefin wherein the at least one aliphatic or aromatic olefin is contacted with the catalyst system of the present invention.


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