The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Apr. 19, 2016

Filed:

Sep. 28, 2011
Applicants:

Brian J. Ingram, Chicago, IL (US);

Vilas G. Pol, Naperville, IL (US);

Donald C. Cronauer, Naperville, IL (US);

Muruganathan Ramanathan, Knoxville, TN (US);

Inventors:

Brian J. Ingram, Chicago, IL (US);

Vilas G. Pol, Naperville, IL (US);

Donald C. Cronauer, Naperville, IL (US);

Muruganathan Ramanathan, Knoxville, TN (US);

Assignee:

UCHICAGO ARGONNE, LLC, Chicago, IL (US);

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C07C 1/20 (2006.01); B01J 21/06 (2006.01); C01G 19/02 (2006.01); C01G 23/047 (2006.01); B82Y 30/00 (2011.01); C07C 1/12 (2006.01); C01F 17/00 (2006.01); B01J 37/08 (2006.01); B01J 37/14 (2006.01); B01J 23/06 (2006.01); B01J 23/10 (2006.01); B01J 23/14 (2006.01); B01J 23/745 (2006.01); B01J 35/00 (2006.01);
U.S. Cl.
CPC ...
B01J 21/063 (2013.01); B01J 23/06 (2013.01); B01J 23/10 (2013.01); B01J 23/14 (2013.01); B01J 23/745 (2013.01); B01J 35/004 (2013.01); B01J 35/0013 (2013.01); B01J 37/08 (2013.01); B01J 37/084 (2013.01); B01J 37/14 (2013.01); B82Y 30/00 (2013.01); C01F 17/0043 (2013.01); C01G 19/02 (2013.01); C01G 23/047 (2013.01); C07C 1/12 (2013.01); C01P 2002/54 (2013.01); C01P 2002/72 (2013.01); C01P 2002/82 (2013.01); C01P 2002/85 (2013.01); C01P 2004/04 (2013.01); C01P 2004/64 (2013.01); C01P 2006/80 (2013.01); C07C 2521/06 (2013.01); C07C 2523/06 (2013.01); C07C 2523/10 (2013.01); C07C 2523/14 (2013.01); C07C 2523/745 (2013.01); Y02P 20/52 (2015.11);
Abstract

In one preferred embodiment, a photocatalyst for conversion of carbon dioxide and water to a hydrocarbon and oxygen comprises at least one nanoparticulate metal or metal oxide material that is substantially free of a carbon coating, prepared by heating a metal-containing precursor compound in a sealed reactor under a pressure autogenically generated by dissociation of the precursor material in the sealed reactor at a temperature of at least about 600° C. to form a nanoparticulate carbon-coated metal or metal oxide material, and subsequently substantially removing the carbon coating. The precursor material comprises a solid, solvent-free salt comprising a metal ion and at least one thermally decomposable carbon- and oxygen-containing counter-ion, and the metal of the salt is selected from the group consisting of Mn, Ti, Sn, V, Fe, Zn, Zr, Mo, Nb, W, Eu, La, Ce, In, and Si.


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