The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Apr. 05, 2016

Filed:

Apr. 01, 2014
Applicant:

Syngenta Participations Ag, Basel, CH;

Inventors:

Christian Lothschuetz, Munchwilen, CH;

Alexandre Christian Saint-Dizier, Munchwilen, CH;

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07F 15/00 (2006.01); B01J 31/24 (2006.01);
U.S. Cl.
CPC ...
C07F 15/0053 (2013.01); B01J 31/2409 (2013.01); B01J 2231/643 (2013.01); B01J 2531/821 (2013.01);
Abstract

The present invention relates to a process for the preparation of a compound of formula (I), wherein X is —CH—, —CH—CH—, —CH—CH—CH— or —CH—CH—CH—CH—; Yis —CH—; —CH—CH— or —NH—; Yis NHRor SH; wherein Ris hydrogen, C-Calkyl or phenyl; R-and R, independently from each other, represent aliphatic or aromatic groups; Rand R, independently from each other, represent aliphatic or aromatic groups; Rand Rare each hydrogen or represent together with the carbon atoms to which they are bonded, a phenyl ring; which process comprises reacting a compound of formula II [RuCI(R)n]m (II), wherein n is 1 and m is >1 which represents a polymeric structure if Ris a molecule containing two alkene or alkyne moieties coordinating in an hapto-2 coordination mode to the metal; or n is 4 and m is 1 if Ris a nitrogen, oxygen or sulfur containing molecule in which said nitrogen, oxygen or sulfur coordinate to the metal; in the presence of an inert solvent which boiling point is from 1 12° C. to 165° C. with a compound of formula (III), wherein R, R, Yand Yare as defined under formula I, and a phosphane of formula IV RRP—X—PRR(iv), wherein R, R, R, Rand X are as defined under formula I.


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