The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Patent No.:

US 9289755 B1

PDF
Full Text
Expired
Date of Patent:
Mar. 22, 2016

Filed:

Oct. 25, 2013
Applicants:

Wenyih Frank Lai, Bridgewater, NJ (US);

Nicholas S. Rollman, Hamburg, PA (US);

Inventors:

Wenyih Frank Lai, Bridgewater, NJ (US);

Nicholas S. Rollman, Hamburg, PA (US);

Assignee:
Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
C01B 39/40 (2006.01); B01J 29/40 (2006.01); B01J 20/18 (2006.01); B01J 20/30 (2006.01);
U.S. Cl.
CPC ...
B01J 29/40 (2013.01); B01J 20/18 (2013.01); B01J 20/3085 (2013.01); C01B 39/40 (2013.01);
Abstract

Methods are provided for synthesizing crystals having a ZSM-5 framework structure from synthesis mixtures suitable for synthesis of ZSM-12 framework structure crystals in the absence of seed crystals with a ZSM-5 framework structure, such as in the absence of any seed crystals. For synthesis mixtures with a sufficiently high XO:YOratio, seeding a synthesis mixture with ZSM-5 seed crystals can result in production of pure phase ZSM-5 crystals with a new morphology. The morphology can include rod-like primary crystallites with a length of about 0.5 μm or less that are organized/aggregated into larger secondary crystal structures. The aggregation of the primary crystallites into a secondary crystal structure can allow for an unexpectedly large mesoporous surface area for the ZSM-5 crystals.


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