The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Mar. 08, 2016

Filed:

Sep. 12, 2013
Applicant:

Exxonmobil Chemical Patents Inc., Baytown, TX (US);

Inventors:

Keith H. Kuechler, Friendswood, TX (US);

Jihad M. Dakka, Whitehouse Station, NJ (US);

James R. Lattner, LaPorte, TX (US);

Christopher L. Becker, Manhattan, KS (US);

Edmund J. Mozeleski, Somerset, NJ (US);

Assignee:
Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
C07C 45/53 (2006.01); C07C 37/08 (2006.01); C07C 2/66 (2006.01); C07C 29/80 (2006.01); C07C 1/24 (2006.01); C07C 2/74 (2006.01); C07C 5/03 (2006.01); C07C 407/00 (2006.01); C07C 29/60 (2006.01);
U.S. Cl.
CPC ...
C07C 45/53 (2013.01); C07C 1/24 (2013.01); C07C 2/66 (2013.01); C07C 2/74 (2013.01); C07C 5/03 (2013.01); C07C 29/60 (2013.01); C07C 29/80 (2013.01); C07C 37/08 (2013.01); C07C 407/00 (2013.01); C07C 2101/14 (2013.01); C07C 2529/70 (2013.01);
Abstract

In a process for producing phenol and/or cyclohexanone, cyclohexylbenzene is contacted with an oxygen-containing gas to produce an oxidation effluent containing cyclohexylbenzene hydroperoxide. At least a portion of the cyclohexylbenzene hydroperoxide is then contacted with a cleavage catalyst to produce a cleavage effluent containing phenol and cyclohexanone and by-products including phenylcyclohexanol. The cleavage effluent or a neutralized product thereof also comprises at least one heteroatom-containing compound, which is separated from the cleavage effluent and/or the neutralized product thereof to leave a cleavage fraction lean in the heteroatom-containing compound and containing at least a portion of the phenylcyclohexanol. At least a portion of the phenylcyclohexanol is then contacted with a dehydration catalyst comprising a molecular sieve of the MCM-22 type to convert at least a portion of the phenylcyclohexanol to phenylcyclohexene.


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