The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Feb. 16, 2016

Filed:

May. 31, 2012
Applicants:

Radu Custelcean, Knoxville, TN (US);

Bruce A. Moyer, Oak Ridge, TN (US);

Arbin Rajbanshi, Knoxville, TN (US);

Inventors:

Radu Custelcean, Knoxville, TN (US);

Bruce A. Moyer, Oak Ridge, TN (US);

Arbin Rajbanshi, Knoxville, TN (US);

Assignee:

UT-BATTELLE, LLC, Oak Ridge, TN (US);

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C07D 213/75 (2006.01); C02F 1/52 (2006.01); C02F 101/00 (2006.01); G21F 9/12 (2006.01); C02F 101/10 (2006.01); C02F 1/58 (2006.01);
U.S. Cl.
CPC ...
C02F 1/52 (2013.01); C02F 1/58 (2013.01); C07D 213/75 (2013.01); G21F 9/12 (2013.01); C02F 2101/006 (2013.01); C02F 2101/101 (2013.01);
Abstract

The present invention relates to urea-functionalized crystalline capsules self-assembled by sodium or potassium cation coordination and by hydrogen-bonding water bridges to selectively encapsulate tetrahedral divalent oxoanions from highly competitive aqueous alkaline solutions and methods using this system for selective anion separations from industrial solutions. The method involves competitive crystallizations using a tripodal tris(urea) functionalized ligand and, in particular, provides a viable approach to sulfate separation from nuclear wastes.


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