The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jan. 12, 2016

Filed:

Apr. 01, 2011
Applicants:

Robert J. Gulotty, Jr., Glendale, AZ (US);

Dean M. Millar, Midland, MI (US);

Albert E. Schweizer, Jr., Port St. Lucie, FL (US);

Raymond M. Collins, Midland, MI (US);

Inventors:

Robert J. Gulotty, Jr., Glendale, AZ (US);

Dean M. Millar, Midland, MI (US);

Albert E. Schweizer, Jr., Port St. Lucie, FL (US);

Raymond M. Collins, Midland, MI (US);

Assignee:

Dow Global Technologies LLC, Midland, MI (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
B01J 37/20 (2006.01); B01J 23/88 (2006.01); B01J 23/882 (2006.01); B01J 27/051 (2006.01); B01J 35/02 (2006.01); B01J 37/00 (2006.01); B01J 37/02 (2006.01); B01J 37/03 (2006.01); B01J 37/08 (2006.01); B01J 37/16 (2006.01); C01G 51/00 (2006.01);
U.S. Cl.
CPC ...
B01J 37/20 (2013.01); B01J 23/88 (2013.01); B01J 23/882 (2013.01); B01J 27/051 (2013.01); B01J 27/0515 (2013.01); B01J 35/023 (2013.01); B01J 37/0045 (2013.01); B01J 37/0236 (2013.01); B01J 37/033 (2013.01); B01J 37/08 (2013.01); B01J 37/16 (2013.01); C01G 51/30 (2013.01);
Abstract

A process for preparing a molybdenum sulfide-based catalyst comprises drying a precipitated molybdenum sulfide-based catalyst precursor, for example, a wet filter cake, such that a particulate catalyst precursor, containing from 12 to 15 percent by weight water, is formed. The particulate catalyst precursor is desirably in the form of free-flowing particles. The particulate catalyst precursor is then auto-reduced. A rotary furnace that subjects the catalyst precursor to at least two zones having distinct temperatures may be conveniently used for drying, auto-reduction, or both. The staged drying and auto-reduction steps reduce the tendency of the precursor to self-heat, which is undesirable because it reduces both the activity and selectivity of the final catalyst.


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