The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jan. 05, 2016

Filed:

Jun. 23, 2011
Applicants:

Parag Rasiklal Shah, Lafayette Hill, PA (US);

Yatao Rachel HU, Malvern, PA (US);

Myoung Kie Lee, King of Prussia, PA (US);

Inventors:

Parag Rasiklal Shah, Lafayette Hill, PA (US);

Yatao Rachel Hu, Malvern, PA (US);

Myoung Kie Lee, King of Prussia, PA (US);

Assignee:

PQ CORPORATION, Malvern, PA (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C08F 4/02 (2006.01); B01J 21/08 (2006.01); B01J 23/26 (2006.01); B01J 35/10 (2006.01); B01J 37/03 (2006.01); B01J 37/06 (2006.01); C08F 10/00 (2006.01);
U.S. Cl.
CPC ...
C08F 4/02 (2013.01); B01J 21/08 (2013.01); B01J 23/26 (2013.01); B01J 35/1023 (2013.01); B01J 35/1047 (2013.01); B01J 37/036 (2013.01); B01J 37/06 (2013.01); C08F 10/00 (2013.01);
Abstract

A process for preparation of silica xerogel catalyst support particles having high surface areas involves ageing a silica hydrogel at a pH from 3 to 5 and at a temperature of 45° C. or more. The ageing at low pH leads to a silica gel which may be converted to a xerogel having a pore volume of 1.5 cm/g or more and a surface area of 600 m/g or more by removal of liquid from the pore structure by solvent exchange with a liquid solvent having a surface tension of 35 mN/m or less. The resulting particles are useful for carrying catalyst metal compounds, such as a chromium compounds, in the pore structure to act as catalyst precursors. These catalyst precursors may be activated into porous catalyst particles suitable for use for olefin polymerization to provide high activity and for forming high molecular weight polymers (low MI polymers) with good crack resistance.


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