The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jan. 05, 2016

Filed:

Apr. 04, 2014
Applicant:

Pretium Ventures Aa, Llc, Houston, TX (US);

Inventors:

Ronnie M. Hanes, Union Grove, AL (US);

Peter P. Hanik, Houston, TX (US);

James A. Hinnenkamp, Houston, TX (US);

Assignee:

Pretium Ventures AA, LLC, Houston, TX (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 51/12 (2006.01); B01J 31/20 (2006.01); C07C 51/50 (2006.01); B01J 8/00 (2006.01);
U.S. Cl.
CPC ...
C07C 51/12 (2013.01); B01J 8/00 (2013.01); B01J 31/20 (2013.01); C07C 51/50 (2013.01); B01J 2219/00006 (2013.01); B01J 2231/321 (2013.01); B01J 2531/822 (2013.01); B01J 2531/827 (2013.01); C07C 2523/46 (2013.01);
Abstract

An alcohol such as methanol is reacted with carbon monoxide in a liquid reaction medium including a catalyst, an alkyl iodide such as methyl iodide, alkyl acetate such as methyl acetate in specified proportions, an additive, and an effective amount of water, where the additive increases an ionic character of the hydrogen iodide bond and the effective amount of water is sufficient to facilitate carboxylic acid release after carbonylation at the catalyst and to reduce anhydride formation. The present reaction system not only provides an acid product at water levels considerable below levels currently used, but also provides unexpected reaction rates and unexpected high catalyst stability.


Find Patent Forward Citations

Loading…