The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Dec. 15, 2015

Filed:

Sep. 27, 2013
Applicant:

Uop Llc, Des Plaines, IL (US);

Inventors:

Chunqing Liu, Arlington Heights, IL (US);

Zara Osman, Glenview, IL (US);

Angela N. Troxell, Chicago, IL (US);

Assignee:

UOP LLC, Des Plaines, IL (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C08G 69/08 (2006.01); B01D 71/62 (2006.01); B01D 67/00 (2006.01);
U.S. Cl.
CPC ...
B01D 71/62 (2013.01); B01D 67/0006 (2013.01); B01D 67/0083 (2013.01); B01D 67/0088 (2013.01); B01D 2323/08 (2013.01); B01D 2323/30 (2013.01);
Abstract

A method of making a polybenzoxazole (PBO) membrane from a self-cross-linked aromatic polyimide polymer membrane is provided. These membranes are useful in the separation of gas mixtures and liquid mixtures. The PBO membrane is made by fabricating a self-cross-linkable aromatic polyimide polymer membrane comprising both hydroxyl functional groups and carboxylic acid functional groups; cross-linking the polymer to form a self-cross-linked aromatic polyimide polymer membrane by heating the membrane at 250° to 300° C. under an inert atmosphere; and thermal heating the self-cross-linked aromatic polyimide polymer membrane at a temperature from about 350° to 500° C. under an inert atmosphere to convert the self-cross-linked aromatic polyimide polymer membrane into a PBO membrane. A membrane coating step may be added by coating the selective layer surface of the PBO membrane with a thin layer of high permeability material.


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