The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Dec. 08, 2015

Filed:

Sep. 13, 2011
Applicants:

Igor Alabugin, Tallahassee, FL (US);

Runa Pal, Tallahassee, FL (US);

Inventors:

Igor Alabugin, Tallahassee, FL (US);

Runa Pal, Tallahassee, FL (US);

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C07C 45/61 (2006.01); C07C 29/68 (2006.01); C07C 41/30 (2006.01); C07C 41/32 (2006.01); C07C 45/51 (2006.01); C07C 45/68 (2006.01); C07F 7/08 (2006.01);
U.S. Cl.
CPC ...
C07C 29/68 (2013.01); C07C 41/30 (2013.01); C07C 41/32 (2013.01); C07C 45/511 (2013.01); C07C 45/61 (2013.01); C07C 45/68 (2013.01); C07F 7/083 (2013.01); C07C 2101/10 (2013.01);
Abstract

A method for preparing a cyclobutene compound or a cyclopentenone is provided. The method comprises contacting an α,β-diketone with a metal acetylide at a temperature below 0° C. to thereby form a reaction mixture comprising a bis-alkyne precursor. The bis-alkyne precursor rearranges into a bis-allenic intermediate, which undergoes further rearrangement into the cyclobutene compound or the cyclopentenone compound as the temperature of the reaction mixture increases from below 0° C. to above 0° C.


Find Patent Forward Citations

Loading…