The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Dec. 01, 2015

Filed:

Mar. 18, 2014
Applicant:

Oakland University, Rochester, MI (US);

Inventors:

Xiangqun Zeng, Rochester Hills, MI (US);

Zhe Wang, Auburn Hills, MI (US);

Assignee:

Oakland University, Rochester, MI (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 27/10 (2006.01); C07C 29/10 (2006.01); C07C 35/00 (2006.01); C07C 29/00 (2006.01); C07C 31/00 (2006.01); C07C 31/02 (2006.01); C07C 33/00 (2006.01); C07C 27/00 (2006.01); C25B 3/00 (2006.01); C25B 3/02 (2006.01); C25B 9/08 (2006.01);
U.S. Cl.
CPC ...
C25B 3/00 (2013.01); C25B 3/02 (2013.01); C25B 9/08 (2013.01);
Abstract

An alkane gas is supplied to an interface between an activated surface of a platinum or palladium working electrode and an ionic liquid electrolyte. The alkane adsorbs at or near an interface complex formed at the interface. The ionic liquid electrolyte is selected from a group consisting of 1-ethyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide, 1-propyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide, 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide, 1-pentyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide, 1-hexyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide, 1-heptyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide, 1-octyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide, 1-nonyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide, and 1-decyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide, and combinations thereof. While the alkane gas in the presence of oxygen is supplied to the interface, positive electrode potential is applied to the platinum or palladium working electrode, which causes oxidation of the adsorbed alkane to form a reaction product. A concentration of the alkane is quantified using an alkane anodic current or current density at the positive electrode potential. The alkane is used as an internal standard to calibrate oxygen detection.


Find Patent Forward Citations

Loading…