The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Dec. 01, 2015

Filed:

Mar. 23, 2011
Applicants:

Johannes Gerardus DE Vries, Maastricht, NL;

Teddy, Groningen, NL;

Pim Huat Phua, Groningen, NL;

Ignacio Vladimiro Melián Cabrera, Groningen, NL;

Hero Jan Heeres, Harkstede, NL;

Inventors:

Johannes Gerardus De Vries, Maastricht, NL;

Teddy, Groningen, NL;

Pim Huat Phua, Groningen, NL;

Ignacio Vladimiro Melián Cabrera, Groningen, NL;

Hero Jan Heeres, Harkstede, NL;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 29/132 (2006.01); C07D 201/08 (2006.01); C07D 313/04 (2006.01);
U.S. Cl.
CPC ...
C07D 313/04 (2013.01); C07C 29/132 (2013.01); C07D 201/08 (2013.01);
Abstract

The present invention relates to a method for preparing caprolactone, comprising converting 5-hydroxymethyl-2-furfuraldehyde by hydrogenation into at least one intermediate compound selected from the group of 2,5-tetrahydrofuran-dimethanol, 1,6-hexanediol and 1,2,6-hexanetriol, and preparing caprolactone from said intermediate compound. Further, the invention relates to a method for preparing 1,2,6-hexanetriol comprising preparing 5-hydroxymethyl-2-furfaldehyde from a renewable source, converting 5-hydroxymethyl-2-furfaldehyde into 2,5-tetrahydrofuran-dimethanol and converting 2,5-tetrahydrofuran-dimethanol into 1,2,6-hexanetriol. Further, the invention relates to a method for preparing 1,6-hexanediol from 1,2,6-hexanetriol, wherein 1,2,6-hexanetriol is subjected to a ring closure reaction, thereby forming (tetrahydro-2H-pyran-2-yl)methanol, and the (tetrahydro-2H-pyran-2-yl)methanol is hydrogenated, thereby forming 1,6-hexane diol.


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