The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Nov. 03, 2015

Filed:

Apr. 26, 2012
Applicants:

Wayne Errol Evans, Richmond, TX (US);

Jeffrey Michael Kobe, Houston, TX (US);

Marek Matusz, Houston, TX (US);

Inventors:

Wayne Errol Evans, Richmond, TX (US);

Jeffrey Michael Kobe, Houston, TX (US);

Marek Matusz, Houston, TX (US);

Assignee:

Shell Oil Company, Houston, TX (US);

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C07D 301/03 (2006.01); C07C 213/04 (2006.01); C07D 301/12 (2006.01);
U.S. Cl.
CPC ...
C07C 213/04 (2013.01); C07D 301/12 (2013.01);
Abstract

Processes for the epoxidation of ethylene are provided in which, following start-up, an epoxidation catalyst is contacted with a feed comprising ethylene, oxygen, carbon dioxide in an amount below 2.0 vol. %, and a chloride moderator to achieve a desired work rate at a first operating temperature T. The composition of the feed is subsequently adjusted (e.g., by decreasing the ethylene concentration, decreasing the oxygen concentration, increasing the carbon dioxide concentration and/or adjusting the concentration of the chloride moderator) so as to increase the first operating temperature Tto a second operating temperature Twhile maintaining the desired work rate. As the catalyst activity declines, the composition of the feed is further adjusted so as to maintain the desired work rate at the second operating temperature T.


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