The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Nov. 03, 2015

Filed:

Nov. 18, 2011
Applicants:

David William Johnson, Wilton Redcar, GB;

Graham Ronald Eastham, Wilton Redcar, GB;

Martyn Poliakoff, Nottingham, GB;

Thomas Andrew Huddle, Guildford, GB;

Inventors:

David William Johnson, Wilton Redcar, GB;

Graham Ronald Eastham, Wilton Redcar, GB;

Martyn Poliakoff, Nottingham, GB;

Thomas Andrew Huddle, Guildford, GB;

Assignee:
Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
C07B 37/06 (2006.01); C07C 51/38 (2006.01); C07C 67/00 (2006.01); C08F 20/06 (2006.01); C08F 20/10 (2006.01); C08F 20/14 (2006.01);
U.S. Cl.
CPC ...
C07C 51/38 (2013.01); C07C 67/00 (2013.01); C08F 20/06 (2013.01); C08F 20/10 (2013.01); C08F 20/14 (2013.01);
Abstract

A process for the production of methacrylic acid is described. The process comprises the base catalysed decarboxylation of at least one or a mixture of dicarboxylic acids selected from itaconic, citraconic or mesaconic acid. The decarboxylation is carried out in the range greater than 240 and up to 275° C. to provide high selectivity. The methacrylic acid product may be esterified to produce an ester. A method of preparing polymers or copolymers of methacrylic acid or methacrylic acid esters using the process is also described. Optionally, the process may be preceded with a decarboxylation and, if necessary, a dehydration step on a source of pre-acid such as citric acid or isocitric acid.


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