The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Nov. 03, 2015

Filed:

May. 02, 2013
Applicant:

The University of North Carolina AT Chapel Hill, Chapel Hill, NC (US);

Inventors:

Maurice Brookhart, Carrboro, NC (US);

Michael Findlater, Chapel Hill, NC (US);

Damien Guironnet, Charlotte, NC (US);

Thomas Warren Lyons, Carrboro, NC (US);

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 2/52 (2006.01); C07C 5/333 (2006.01); C07C 2/72 (2006.01); C07C 5/32 (2006.01); C07C 5/42 (2006.01); C07C 5/52 (2006.01);
U.S. Cl.
CPC ...
C07C 2/72 (2013.01); C07C 2/52 (2013.01); C07C 5/321 (2013.01); C07C 5/42 (2013.01); C07C 5/52 (2013.01); C07C 2101/16 (2013.01); C07C 2531/22 (2013.01);
Abstract

A method of making para-xylene or toluene is carried out by: (a) reacting a C5 or C6 linear monoene (itself, or formed from a C5 or C6 linear alkane) with a hydrogen acceptor in the presence of a hydrogen transfer catalyst to produce a C5 or C6 diene; (b) reacting the C5-C6 diene with ethylene to produce a cyclohexene having 1 or 2 methyl groups substituted thereon; and then (c) either (i) dehydrogenating the cyclohexene in the presence of a hydrogen acceptor with a hydrogen transfer catalyst to produce a compound selected from the group consisting of para-xylene and toluene, or (ii) dehydrogenating the cyclohexene in the absence of a hydrogen acceptor with a dehydrogenation catalyst, to produce para-xylene or toluene.


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