The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Oct. 20, 2015

Filed:

Jul. 23, 2010
Applicants:

Jonathan Alec Forsyth, Newbury, GB;

Yasushi Mori, Hiroshima, JP;

Kazumasa Ogura, Tokyo, JP;

Inventors:

Jonathan Alec Forsyth, Newbury, GB;

Yasushi Mori, Hiroshima, JP;

Kazumasa Ogura, Tokyo, JP;

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C10K 1/00 (2006.01); B01D 53/00 (2006.01); C01B 3/16 (2006.01); C01B 3/34 (2006.01); C01B 3/50 (2006.01); C01B 3/52 (2006.01); C01B 17/16 (2006.01); C10K 1/16 (2006.01); F25J 3/06 (2006.01); B01D 53/14 (2006.01);
U.S. Cl.
CPC ...
C10K 1/005 (2013.01); B01D 53/002 (2013.01); C01B 3/16 (2013.01); C01B 3/34 (2013.01); C01B 3/506 (2013.01); C01B 3/52 (2013.01); C01B 17/167 (2013.01); C10K 1/004 (2013.01); C10K 1/165 (2013.01); F25J 3/067 (2013.01); F25J 3/0625 (2013.01); F25J 3/0655 (2013.01); B01D 53/1462 (2013.01); B01D 53/1468 (2013.01); B01D 2257/304 (2013.01); B01D 2257/504 (2013.01); C01B 2203/0283 (2013.01); C01B 2203/046 (2013.01); C01B 2203/0415 (2013.01); C01B 2203/0475 (2013.01); C01B 2203/0485 (2013.01); C01B 2203/0495 (2013.01); C01B 2203/0883 (2013.01); C01B 2203/0894 (2013.01); C01B 2203/84 (2013.01); F25J 3/0675 (2013.01); F25J 2205/40 (2013.01); F25J 2205/50 (2013.01); F25J 2210/04 (2013.01); F25J 2220/82 (2013.01); F25J 2220/84 (2013.01); F25J 2230/30 (2013.01); F25J 2245/02 (2013.01); F25J 2270/06 (2013.01); F25J 2270/20 (2013.01); Y02C 10/12 (2013.01);
Abstract

A process is described for separating a gas stream containing hydrogen sulfide (HS) impurities into a hydrogen (H) rich vapor stream, a carbon dioxide (CO) stream and an HS rich vapor stream in an apparatus that comprises a compression and/or cooling system comprising at least one compressor and/or heat exchanger and a gas-liquid separator vessel, and an HS recovery unit. In examples, the process comprises the steps of: (a) feeding the gas stream to the compression and/or cooling system such that carbon dioxide in the gas stream condenses to form a two-phase stream; (b) passing the two-phase stream either directly or indirectly to a gas-liquid separator vessel and withdrawing a hydrogen rich vapor stream and a liquid COstream containing dissolved HS impurities from the separator vessel; (c) passing the liquid COstream containing dissolved HS impurities to an HS recovery unit comprising an evaporator/condenser in which the COand HS are vaporized and an HS absorber in which the gaseous HS and COare separated, wherein the two phase stream passed to the separator is at a pressure of from 80 bar to 400 bar. In some applications, the pressure of the HS recovery unit is at least 30 bar. In a preferred example, residual COin the hydrogen rich vapor stream is removed in an optional step by solvent extraction in a COabsorber most preferably in a configuration where the HS and COabsorbers share the same (preferably methanol) solvent.


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