The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Oct. 13, 2015

Filed:

Jul. 06, 2011
Applicants:

Xuehui Dong, Akron, OH (US);

Wenbin Zhang, Akron, OH (US);

Stephen Z. D. Cheng, Akron, OH (US);

Roderic P. Quirk, Akron, OH (US);

Inventors:

Xuehui Dong, Akron, OH (US);

Wenbin Zhang, Akron, OH (US);

Stephen Z. D. Cheng, Akron, OH (US);

Roderic P. Quirk, Akron, OH (US);

Assignee:

The University of Akron, Akron, OH (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 69/52 (2006.01); C01B 31/02 (2006.01); C07C 17/16 (2006.01); C07C 23/18 (2006.01); C07C 29/42 (2006.01); C07C 29/68 (2006.01); C07C 35/44 (2006.01); C07C 69/606 (2006.01); C07C 69/63 (2006.01);
U.S. Cl.
CPC ...
C01B 31/0213 (2013.01); C07C 17/16 (2013.01); C07C 23/18 (2013.01); C07C 29/42 (2013.01); C07C 29/68 (2013.01); C07C 35/44 (2013.01); C07C 69/606 (2013.01); C07C 69/63 (2013.01); C07C 2104/00 (2013.01);
Abstract

The preparation of novel fullerynes which are fullerenes (e.g. C, C, C, etc.) that contain one or more alkyne functionalities and may contain additional functional groups such as hydroxyls, halogens, esters, haloesters, phenyl, oligo(ethylene glycol)s, perfluorinated alkyl chains, and the like. Two desired preparation routes are disclosed. The first one is the Fischer esterification in desired solvents using a special designed reactor in contrast to the heretofore initial Steglich reaction that results in side reactions and low yields. The second one uses acetylide Grignard reagents that have reduced nucleophilicity and higher stability in contrast to the use of heretofore initial lithium organyls or other Grignard reagents that would add to Cwith possible multi-additions in an uncontrollable manner.


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