The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Oct. 06, 2015

Filed:

Aug. 28, 2012
Applicants:

Xiangqun Zeng, Rochester Hills, MI (US);

Zhe Wang, Auburn Hills, MI (US);

Inventors:

Xiangqun Zeng, Rochester Hills, MI (US);

Zhe Wang, Auburn Hills, MI (US);

Assignee:

Oakland University, Rochester, MI (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 27/10 (2006.01); C07C 29/10 (2006.01); C07C 35/00 (2006.01); C07C 29/00 (2006.01); C07C 31/00 (2006.01); C07C 31/02 (2006.01); C07C 33/00 (2006.01); C07C 27/00 (2006.01); C25B 3/02 (2006.01); C25B 3/00 (2006.01); C25B 9/08 (2006.01);
U.S. Cl.
CPC ...
C25B 3/02 (2013.01); C25B 3/00 (2013.01); C25B 9/08 (2013.01);
Abstract

An aerobic method for oxidizing an alkane is disclosed herein. At least a portion of a surface of a platinum working electrode is activated at an interface between the platinum working electrode and an ionic liquid electrolyte (i.e., 1-ethyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide, 1-propyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide, 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide, 1-pentyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide, 1-hexyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide, 1-heptyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide, 1-octyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide, 1-nonyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide, and 1-decyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imidem, and combinations thereof). An interface complex is formed at the interface. An alkane gas is supplied to the interface. The alkane adsorbs at or near the interface complex. The alkane gas in the presence of oxygen is supplied to the interface. While the alkane gas in the presence of oxygen is supplied to the interface, a positive electrode potential is applied to the platinum working electrode, which causes a reactive oxygen species formed at the interface to catalyze oxidation of the adsorbed alkane to form a reaction product.


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