The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.
The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.
Patent No.:
Date of Patent:
Sep. 01, 2015
Filed:
Jun. 22, 2010
Avelino Corma, Valencia, ES;
Cristina Martinez, Valencia, ES;
Eric J. Doskocil, Oswego, IL (US);
George Yaluris, Park Ridge, IL (US);
Avelino Corma, Valencia, ES;
Cristina Martinez, Valencia, ES;
Eric J. Doskocil, Oswego, IL (US);
George Yaluris, Park Ridge, IL (US);
BP Oil International Limited, Sunbury on Thames, GB;
BP Corporation North America Inc., Houston, TX (US);
Abstract
A modified zeolite catalyst derived from a zeolite of a structural type which consists of a one-dimensional micropore structure of channels made from rings containing between 8 and 12 silicon/aluminum atoms is disclosed. It consists substantially of a plurality of crystallites having additional mesoporosity whose volume is in the range 0.09 to 0.25 cc/g as mentioned by nitrogen adsorption at 77° K and calculated by the BJH method. The mesoporosity may be introduced into the crystallites by e.g. treatment with aqueous sodium hydroxide at a pH at 25° C. in excess of 8 for an extended period at elevated temperature. The catalyst shows improved resistance to catalyst deactivation and greater selectivity to higher hydrocarbons when used to e.g. oligomerize light alkenes e.g. propene or the butenes.