The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Aug. 18, 2015

Filed:

Oct. 24, 2011
Applicants:

Ichiro Araya, Tochigi, JP;

Koichi Kiyota, Tochigi, JP;

Muneki Nagao, Tochigi, JP;

Inventors:

Ichiro Araya, Tochigi, JP;

Koichi Kiyota, Tochigi, JP;

Muneki Nagao, Tochigi, JP;

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07D 207/16 (2006.01); C07D 207/24 (2006.01); C07B 53/00 (2006.01); C07C 269/06 (2006.01); C07C 227/18 (2006.01); C07D 207/277 (2006.01);
U.S. Cl.
CPC ...
C07D 207/24 (2013.01); C07B 53/00 (2013.01); C07C 227/18 (2013.01); C07C 269/06 (2013.01); C07D 207/16 (2013.01); C07D 207/277 (2013.01); C07C 2101/02 (2013.01);
Abstract

The present invention provides an inexpensive and industrially advantageous method for producing an optically active form of an anti-(3S,4R)-3-alkylcarbamoyl-4-hydroxypyrrolidine derivative or it's enantiomer, which is a key intermediate for producing a high-quality optically active form of (3R,4S)-3-alkylaminomethyl-4-fluoropyrrolidine or it's enantiomer useful as an intermediate for producing pharmaceuticals. The present invention relates to a method for producing an optically active anti-(3S,4R)-4-hydroxypyrrolidine-3-carboxamide derivative, or it's enantiomer by carrying out asymmetric hydrogenation using an optically active catalyst of a 4-oxopyrrolidine-3-carboxamide derivative represented by the general formula (I). [in the formula (I), PGrepresents a protective group for an amino group, and Rrepresents hydrogen, a C1 to C6 alkyl group which may be substituted, or a C3 to C8 cycloalkyl group which may be substituted].


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