The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jul. 07, 2015

Filed:

Dec. 14, 2011
Applicants:

Peter E. Groenendijk, Hulst, NL;

Cornelis Hovingh, Aardenburg, NL;

Inventors:

Peter E. Groenendijk, Hulst, NL;

Cornelis Hovingh, Aardenburg, NL;

Assignee:

Dow Global Technologies LLC, Midland, MI (US);

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C07C 1/04 (2006.01); C07C 29/16 (2006.01); C07C 1/24 (2006.01);
U.S. Cl.
CPC ...
C07C 1/0485 (2013.01); C07C 29/16 (2013.01); C07C 1/04 (2013.01); C07C 1/24 (2013.01); C07C 2521/04 (2013.01); C07C 2521/06 (2013.01);
Abstract

Conversion of synthesis gas to propylene is enhanced via a stepped process wherein a Fischer-Tropsch reaction is first carried out, followed by recovery of propylene produced thereby and then use of product ethylene and unreacted syngas in a hydroformylation reaction to produce propanol, which is then dehydrated to form additional propylene. The process enables significant enhancement of propylene yield that is efficient and makes use of ethylene that is a byproduct of Fischer-Tropsch processes that are employed primarily for production of higher olefins, such as hexene and octene. Thus, it can be carried out in conjunction with already on-line Fischer-Tropsch facilities.


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