The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jun. 30, 2015

Filed:

Sep. 14, 2011
Applicants:

Dan LI, Shantou, CN;

Xiaoping Zhou, Shantou, CN;

Jie Liu, Shantou, CN;

Inventors:

Dan Li, Shantou, CN;

Xiaoping Zhou, Shantou, CN;

Jie Liu, Shantou, CN;

Assignee:

Other;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
B01J 20/22 (2006.01); C07F 1/08 (2006.01); C07F 3/00 (2006.01); C07F 15/04 (2006.01); C07F 13/00 (2006.01); C07F 1/00 (2006.01); C07F 3/06 (2006.01);
U.S. Cl.
CPC ...
C07F 15/045 (2013.01); B01J 20/22 (2013.01); C07F 13/005 (2013.01); C07F 1/005 (2013.01); C07F 3/00 (2013.01); C07F 1/08 (2013.01); C07F 3/06 (2013.01);
Abstract

The present invention discloses zeolite metal bis(imidazole) coordination polymers and preparation method thereof. The new class of zeolite coordination polymers of the present invention is a chemical compound with the following general chemical formula {[M(BIm)]×xDMF×yCHO×zHO}, in which when M=Zn, x=0.9, y=0, z=0; when M=Cu, x=1.2, y=0, z=0; when M=Mn, x=2.0, y=0, z=0; when M=Ni, x=0.4, y=1.2, z=1.0, BIm is 1,2-bis((5H-imidazol-4-yl)methylene)hydrazine, DMF is N,N-dimethyl formamide, HO is water. A solvothermal method or slow diffusion is used on the compounds to obtain crystals of high purity. The coordination polymers of the present invention have good thermal stability, and have strong adsorption performance for COunder conditions of 0° C. and normal pressure as adsorbent materials.


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