The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jun. 30, 2015

Filed:

Dec. 02, 2013
Applicant:

Wisconsin Alumni Research Foundation, Madison, WI (US);

Inventors:

James A. Dumesic, Verona, WI (US);

Juan Carlos Serrano Ruiz, Madison, WI (US);

Ryan M. West, Madison, WI (US);

Assignee:
Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
C07D 307/00 (2006.01); C07C 6/00 (2006.01); C07C 51/00 (2006.01); C07D 309/12 (2006.01); B01J 23/648 (2006.01); B01J 35/00 (2006.01); C01B 3/32 (2006.01); C07C 1/213 (2006.01); C07C 1/24 (2006.01); C07C 51/09 (2006.01); C07D 307/33 (2006.01); C10G 3/00 (2006.01); B01J 23/10 (2006.01); B01J 35/10 (2006.01);
U.S. Cl.
CPC ...
C07D 309/12 (2013.01); B01J 23/10 (2013.01); B01J 23/6484 (2013.01); B01J 35/0006 (2013.01); B01J 35/1019 (2013.01); C01B 3/32 (2013.01); C01B 2203/0233 (2013.01); C01B 2203/06 (2013.01); C01B 2203/065 (2013.01); C01B 2203/1211 (2013.01); C07C 1/213 (2013.01); C07C 1/24 (2013.01); C07C 51/09 (2013.01); C07C 2521/12 (2013.01); C07C 2527/054 (2013.01); C07C 2527/08 (2013.01); C07C 2527/11 (2013.01); C07C 2527/1206 (2013.01); C07C 2527/173 (2013.01); C07C 2531/04 (2013.01); C07D 307/33 (2013.01); C10G 3/42 (2013.01); C10G 3/45 (2013.01); C10G 3/47 (2013.01); C10G 2300/1014 (2013.01); C10G 2400/20 (2013.01); C07C 51/00 (2013.01);
Abstract

Described is a method to make liquid chemicals. The method includes deconstructing cellulose to yield a product mixture comprising levulinic acid and formic acid, converting the levulinic acid to γ-valerolactone, and converting the γ-valerolactone to pentanoic acid. Alternatively, the γ-valerolactone can be converted to a mixture of n-butenes. The pentanoic acid can be decarboxylated yield 1-butene or ketonized to yield 5-nonanone. The 5-nonanone can be hydrodeoxygenated to yield nonane, or 5-nonanone can be reduced to yield 5-nonanol. The 5-nonanol can be dehydrated to yield nonene, which can be dimerized to yield a mixture of Cand Colefins, which can be hydrogenated to yield a mixture of alkanes.


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