The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jun. 16, 2015

Filed:

Oct. 17, 2011
Applicants:

Peter Edward James Abbott, Eaglescliffe, GB;

Norman Macleod, Hartlepool, GB;

Gordon Edward Wilson, Stockton-on-Tees, GB;

Inventors:

Peter Edward James Abbott, Eaglescliffe, GB;

Norman Macleod, Hartlepool, GB;

Gordon Edward Wilson, Stockton-on-Tees, GB;

Assignee:

Johnson Matthey PLC, London, GB;

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C10L 3/08 (2006.01); C01B 3/58 (2006.01); C10G 2/00 (2006.01); C10K 1/20 (2006.01); C10K 1/32 (2006.01); C10J 3/00 (2006.01); B01D 53/04 (2006.01); B01J 20/08 (2006.01); B01J 20/28 (2006.01); B01J 20/30 (2006.01); B01J 20/02 (2006.01); B01D 53/02 (2006.01);
U.S. Cl.
CPC ...
C10L 3/08 (2013.01); C01B 3/58 (2013.01); C01B 2203/0485 (2013.01); C01B 2203/061 (2013.01); C10G 2/32 (2013.01); C10G 2300/1011 (2013.01); C10K 1/20 (2013.01); C10K 1/32 (2013.01); C01B 2203/042 (2013.01); C01B 2203/0445 (2013.01); C01B 2203/047 (2013.01); C01B 2203/0495 (2013.01); C10G 2300/1022 (2013.01); C10G 2300/202 (2013.01); C10J 3/00 (2013.01); C10J 2300/093 (2013.01); C10J 2300/1618 (2013.01); C10L 2290/04 (2013.01); C10L 2290/02 (2013.01); C10L 2290/10 (2013.01); C10L 2290/06 (2013.01); C10L 2290/08 (2013.01); C10L 2290/542 (2013.01); B01D 53/02 (2013.01); B01D 53/04 (2013.01); B01D 2253/104 (2013.01); B01D 2253/1122 (2013.01); B01D 2253/1124 (2013.01); B01D 2257/306 (2013.01); B01J 20/08 (2013.01); B01J 20/2803 (2013.01); B01J 20/3028 (2013.01); B01J 20/0237 (2013.01); B01J 20/0244 (2013.01); B01J 20/28004 (2013.01); B01J 20/28016 (2013.01);
Abstract

A process for reducing the thiophene content in a synthesis gas mixture, comprises the steps of (i) passing a synthesis gas mixture comprising hydrogen and carbon oxides and containing thiophene over a copper-containing sorbent disposed in a sorbent vessel at an inlet temperature in the range 200-280° C., (ii) withdrawing a thiophene depleted synthesis gas containing methanol from the sorbent vessel, and (iii) adjusting the temperature of the methanol-containing thiophene-depleted synthesis gas mixture. The resulting gas mixture may be used for production of chemicals, e.g. methanol production or for the Fischer-Tropsch synthesis of liquid hydrocarbons, for hydrogen production by using water gas shift, or for the production of synthetic natural gas.


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