The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Patent No.:

US 9052289 B1

PDF
Full Text
Expired
Date of Patent:
Jun. 09, 2015

Filed:

Dec. 13, 2010
Applicants:

Jimmy Lawrence, Cambridge, MA (US);

Ronald Van Hal, Watertown, MA (US);

Jane Lam, Randolph, MA (US);

Inventors:

Jimmy Lawrence, Cambridge, MA (US);

Ronald van Hal, Watertown, MA (US);

Jane Lam, Randolph, MA (US);

Assignee:
Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
G01N 33/24 (2006.01); G01N 33/22 (2006.01); G01N 33/18 (2006.01); G01N 21/64 (2006.01); G01N 21/31 (2006.01); G01N 33/00 (2006.01); C09K 8/532 (2006.01);
U.S. Cl.
CPC ...
G01N 21/643 (2013.01); Y10T 436/184 (2015.01); G01N 21/31 (2013.01); G01N 33/004 (2013.01); C09K 8/532 (2013.01); C09K 2208/20 (2013.01);
Abstract

Methods and related apparatuses and mixtures are described for spectroscopic detection of hydrogen sulfide in a fluid, for example a formation fluid downhole. A reagent mixture is combined with the fluid. The reagent mixture includes metal ions for reacting with hydrogen sulfide forming a metal sulfide, and a capping agent that limits growth of the insoluble metal sulfide species by electrosteric or steric stabilization. The particle growth is one of chemical reaction or significant aggregation, and the capping agent further functionalizes the reagent mixture to exhibit properties outside the natural characteristics of the metal sulfide species to allow for spectroscopic detection of the metal sulfide species. The combined mixture and fluid is then spectroscopically interrogated to detect the presence of the metal sulfide thereby indicating the presence of hydrogen sulfide in the fluid. The mixture also includes chelating ligands for sustaining thermal endurance of the mixture under downhole conditions.


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