The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jun. 09, 2015

Filed:

Oct. 06, 2011
Applicants:

Stéphane Levasseur, Brussels, BE;

Michèle Van Thournout, Isières, BE;

Pierre Gibot, Amiens, FR;

Christian Masquelier, Boves, FR;

Inventors:

Stéphane Levasseur, Brussels, BE;

Michèle Van Thournout, Isières, BE;

Pierre Gibot, Amiens, FR;

Christian Masquelier, Boves, FR;

Assignees:

Umicore, Brussels, BE;

Centre National de la Recherche Scientifique, Paris Cedex, FR;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
H01B 1/08 (2006.01); H01B 1/06 (2006.01); C01B 25/45 (2006.01); B82Y 30/00 (2011.01); H01M 4/136 (2010.01); H01M 4/58 (2010.01); H01M 4/02 (2006.01); H01M 10/052 (2010.01);
U.S. Cl.
CPC ...
C01B 25/45 (2013.01); H01B 1/08 (2013.01); H01B 1/06 (2013.01); B82Y 30/00 (2013.01); H01M 4/02 (2013.01); H01M 4/136 (2013.01); H01M 4/5825 (2013.01); H01M 10/052 (2013.01); H01M 2004/021 (2013.01); Y02E 60/122 (2013.01);
Abstract

The invention relates to crystalline nanometric olivine-type LiFeMPOpowder with M being Co and/or Mn, and 0≦x≦1, with small particle size and narrow particle size distribution. A direct precipitation process is described, comprising the steps of: providing a water-based mixture having at a pH between 6 and 10, containing a dipolar aprotic additive, and Li, Fe, P, and Coand/or Mnas precursor components; heating said water-based mixture to a temperature less than or equal to its boiling point at atmospheric pressure, thereby precipitating crystalline LiFeMPOpowder. An extremely fine particle size is obtained of about 80 nm for Mn and 275 nm for Co, both with a narrow distribution.


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