The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jun. 09, 2015

Filed:

Jun. 25, 2013
Applicant:

University of Tennessee Research Foundation, Knoxville, TN (US);

Inventors:

David Matthew Jenkins, Knoxville, TN (US);

Steven Alan Cramer, Knoxville, TN (US);

Zheng Lu, Knoxville, TN (US);

Assignee:
Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
C07F 1/10 (2006.01); C07F 15/02 (2006.01); B01J 31/22 (2006.01); B01J 23/745 (2006.01); C07D 203/14 (2006.01); C07D 203/26 (2006.01); C07F 17/02 (2006.01);
U.S. Cl.
CPC ...
B01J 31/2273 (2013.01); C07D 203/14 (2013.01); B01J 31/2295 (2013.01); C07D 203/26 (2013.01); C07F 17/02 (2013.01); C07F 15/02 (2013.01); C07F 1/10 (2013.01); B01J 2231/74 (2013.01); B01J 2531/0258 (2013.01); B01J 2531/62 (2013.01); B01J 2531/821 (2013.01); B01J 2531/828 (2013.01); B01J 2531/842 (2013.01); B01J 2531/845 (2013.01);
Abstract

Disclosed are metal-bound tetracarbene catalysts, such as iron based aziridination catalyst, having the formula: wherein X is a group 6, 7, 8, 9, or 10 metal and wherein Z is a hydrogen, alkyl, aryl or organic group, wherein the alkyl, aryl or organic group is optionally are independently substituted. In a specific example, a metal-bound tetracarbene catalyst has the formula: Also disclosed are methods of making (synthesizing), transmetallation reagents, these agents, metal-bound tetracarbene catalysts, and a method of catalytic alkene aziridination, using the disclosed metal-bound tetracarbene catalysts.


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