The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Apr. 28, 2015

Filed:

Aug. 24, 2012
Applicants:

Atsushi Goto, Uji, JP;

Hironori Kaji, Uji, JP;

Inventors:

Atsushi Goto, Uji, JP;

Hironori Kaji, Uji, JP;

Assignee:

Kyoto University, Kyoto, JP;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C08F 4/00 (2006.01); C07C 211/62 (2006.01); C07F 9/54 (2006.01); C08F 212/08 (2006.01); C08F 220/18 (2006.01); C08F 220/20 (2006.01); C08F 220/34 (2006.01); C08F 220/44 (2006.01); C08F 220/10 (2006.01); C08F 220/14 (2006.01); C08F 220/28 (2006.01); C08F 220/32 (2006.01);
U.S. Cl.
CPC ...
C08F 4/00 (2013.01); C08F 212/08 (2013.01); C08F 220/14 (2013.01); C08F 220/18 (2013.01); C08F 220/20 (2013.01); C08F 220/34 (2013.01); C08F 220/44 (2013.01); C08F 2220/1825 (2013.01); C08F 2220/1841 (2013.01); C08F 2220/1883 (2013.01); C08F 2220/286 (2013.01); C08F 2220/325 (2013.01);
Abstract

A nonmetallic compound having an ionic bond with a halide ion is used as a catalyst for living radical polymerization. Even if a radical initiator is not used, a monomer can be subjected to a radical polymerization to obtain a polymer having narrow molecular weight distribution. The cost of the living radical polymerization can be remarkably reduced, and it is made possible to prevent adverse effects of using a radical initiator (such as side reactions). The present invention is significantly more environmentally friendly and economically excellent than conventional living radical polymerization methods, due to advantages such as low toxicity of the catalyst, low amount of the catalyst necessary, high solubility of the catalyst, mild reaction conditions, and no coloration/no odor, etc. The catalyst can be applied to various monomers and enables synthesis of high molecular weight polymers.


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