The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Apr. 21, 2015

Filed:

Jun. 24, 2010
Applicants:

Hartmut Yersin, Sinzing, DE;

Uwe Monkowius, Linz, AT;

Tobias Fisher, Falkenstein, DE;

Thomas Hofbeck, Freystadt, DE;

Thomas Baumann, Karlsruhe, DE;

Tobias Grab, Karlsruhe, DE;

Inventors:

Hartmut Yersin, Sinzing, DE;

Uwe Monkowius, Linz, AT;

Tobias Fisher, Falkenstein, DE;

Thomas Hofbeck, Freystadt, DE;

Thomas Baumann, Karlsruhe, DE;

Tobias Grab, Karlsruhe, DE;

Assignee:

Cynora GmbH, Eggenstein-Leopoldshafen, DE;

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C07F 15/00 (2006.01); C07F 9/00 (2006.01); C07F 9/62 (2006.01); C07F 1/00 (2006.01); C07F 9/58 (2006.01); H01L 51/00 (2006.01); C07F 9/6512 (2006.01); H01L 51/50 (2006.01);
U.S. Cl.
CPC ...
C07F 1/005 (2013.01); C07F 9/62 (2013.01); Y02E 10/52 (2013.01); H01L 51/5012 (2013.01); C07F 9/587 (2013.01); Y02E 10/549 (2013.01); H01L 51/0091 (2013.01); H01L 51/009 (2013.01); C07F 9/65122 (2013.01);
Abstract

The invention relates to copper(I) complexes of the formula A wherein X=Cl, Br or I (independently of one another); N*∩E=a bidentate ligand, wherein E=a phosphinyl group including a phosphorus atom or an arsenyl group including an arsenic atom, wherein the phosphinyl group or the arsenyl group is combined with R in the form of RE (where R=alkyl, aryl, alkoxy, or phenoxy; N*=imine function which is part of an aromatic group selected from pyridyl, pyrimidyl, pyridazinyl, triazinyl, oxazolyl, thiazolyl and imidazolyl, the aromatic group optionally having at least one substituent to increase the solubility of the copper(I) complex in an organic solvent; and ∩=at least one carbon atom which is likewise part of the aromatic group. The carbon atom is located directly adjacent both to the imine nitrogen atom, coordinating to Cu in the case of a bridging ligand and to the phosphorus or arsenic atom. The invention also relates to the use of the copper(I) complexes in optoelectronic assemblies, especially in Organic Light Emitting Diodes (OLEDs).


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