The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Mar. 31, 2015

Filed:

Mar. 14, 2013
Applicant:

Eastman Chemical Company, Kingsport, TN (US);

Inventors:

Venkata Bharat Ram Boppana, Johnson City, TN (US);

David William Norman, Kingsport, TN (US);

Melissa Dawn Page, Gate City, VA (US);

Assignee:

Eastman Chemical Company, Kingsport, TN (US);

Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
B01J 27/198 (2006.01); C07C 51/377 (2006.01); B01J 37/03 (2006.01); B01J 21/06 (2006.01); B01J 35/00 (2006.01); C07C 51/09 (2006.01);
U.S. Cl.
CPC ...
B01J 27/198 (2013.01); C07C 51/377 (2013.01); B01J 37/031 (2013.01); B01J 21/063 (2013.01); B01J 35/002 (2013.01); B01J 2523/00 (2013.01); C07C 51/09 (2013.01);
Abstract

The invention relates to a catalyst composition comprising a mixed oxide of vanadium, titanium, and phosphorus. The titanium component is derived from a water-soluble, redox-active organo-titanium compound. The catalyst composition is highly effective at facilitating the vapor-phase condensation of formaldehyde with acetic acid to generate acrylic acid, particularly using an industrially relevant aqueous liquid feed. Additionally, the catalyst composition is catalytically active towards the formation of acrylic acid from methylene diacetate and methacrylic acid from methylene dipropionate; both reactions are carried out with high space time yields.


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