The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Mar. 24, 2015

Filed:

Mar. 30, 2010
Applicants:

Robert Van Den Berg, Amsterdam, NL;

Matthieu Simon Henri Fleys, Amsterdam, NL;

Mark Jan Prins, Amsterdam, NL;

Cornelis Jacobus Smit, Amsterdam, NL;

Alex Frederik Woldhuis, Amsterdam, NL;

Inventors:

Robert Van Den Berg, Amsterdam, NL;

Matthieu Simon Henri Fleys, Amsterdam, NL;

Mark Jan Prins, Amsterdam, NL;

Cornelis Jacobus Smit, Amsterdam, NL;

Alex Frederik Woldhuis, Amsterdam, NL;

Assignee:

Shell Oil Company, Houston, TX (US);

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C09K 8/60 (2006.01); C01B 3/38 (2006.01); C01C 1/00 (2006.01); C01B 3/58 (2006.01); B01D 53/00 (2006.01); B01D 53/14 (2006.01); B01D 53/22 (2006.01); B01D 53/75 (2006.01); B01D 53/86 (2006.01); B01D 71/02 (2006.01); B01D 71/52 (2006.01); B01D 71/56 (2006.01); B01D 71/64 (2006.01); B01D 71/80 (2006.01); C01B 3/16 (2006.01); C01B 3/50 (2006.01); C01B 3/52 (2006.01);
U.S. Cl.
CPC ...
C01B 3/58 (2013.01); B01D 53/002 (2013.01); B01D 53/1462 (2013.01); B01D 53/1493 (2013.01); B01D 53/22 (2013.01); B01D 53/228 (2013.01); B01D 53/75 (2013.01); B01D 53/8668 (2013.01); B01D 71/028 (2013.01); B01D 71/52 (2013.01); B01D 71/56 (2013.01); B01D 71/64 (2013.01); B01D 71/80 (2013.01); C01B 3/16 (2013.01); C01B 3/501 (2013.01); C01B 3/506 (2013.01); C01B 3/52 (2013.01); B01D 2251/206 (2013.01); B01D 2251/80 (2013.01); B01D 2256/16 (2013.01); B01D 2256/20 (2013.01); B01D 2257/304 (2013.01); B01D 2257/308 (2013.01); B01D 2257/408 (2013.01); B01D 2257/504 (2013.01); C01B 2203/0415 (2013.01); C01B 2203/0435 (2013.01); C01B 2203/0475 (2013.01); C01B 2203/0485 (2013.01); Y02C 10/06 (2013.01); Y02C 10/10 (2013.01);
Abstract

A process for producing a purified synthesis gas stream from a feed synthesis gas stream comprising besides the main constituents carbon monoxide and hydrogen also hydrogen sulphide, HCN and/or COS, the process comprising the steps of: (a) removing HCN and/or COS by contacting the feed synthesis gas stream with a catalyst in a HCN/COS reactor in the presence of steam/water, to obtain a synthesis gas stream depleted in HCN and/or in COS; (b) converting hydrogen sulphide in the synthesis gas stream depleted in HCN and/or in COS to elemental sulphur, by contacting the synthesis gas stream with an aqueous reactant solution containing solubilized Fe(III) chelate of an organic acid, at a temperature below the melting point of sulphur, and at a sufficient solution to gas ratio and conditions effective to convert HS to sulphur and inhibit sulphur deposition, to obtain a synthesis gas stream depleted in hydrogen sulphide; (c) removing carbon dioxide from the synthesis gas stream depleted in hydrogen sulphide, to obtain the purified synthesis gas stream and a gas stream enriched in CO.


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