The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Mar. 24, 2015

Filed:

Mar. 12, 2014
Applicant:

Nederlandse Organisatie Voor Wetenschappelijk Onderzoek (Nwo), The Hague, NL;

Inventors:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
B01J 31/00 (2006.01); B01J 27/128 (2006.01); B01J 23/745 (2006.01); B01J 21/04 (2006.01); B01J 21/18 (2006.01); B01J 23/889 (2006.01); B01J 27/224 (2006.01); B01J 35/10 (2006.01); B01J 37/02 (2006.01); B01J 37/03 (2006.01); B82Y 30/00 (2011.01); C07C 1/04 (2006.01);
U.S. Cl.
CPC ...
B01J 23/745 (2013.01); B01J 21/04 (2013.01); B01J 21/185 (2013.01); B01J 23/8892 (2013.01); B01J 27/224 (2013.01); B01J 35/1014 (2013.01); B01J 35/1019 (2013.01); B01J 35/1038 (2013.01); B01J 35/1042 (2013.01); B01J 37/0201 (2013.01); B01J 37/0203 (2013.01); B01J 37/0211 (2013.01); B01J 37/035 (2013.01); B82Y 30/00 (2013.01); C07C 1/044 (2013.01); C07C 1/0445 (2013.01); C07C 2521/04 (2013.01); C07C 2521/18 (2013.01); C07C 2523/745 (2013.01); C10G 2400/20 (2013.01); C10G 2300/1022 (2013.01); C10G 2300/4006 (2013.01);
Abstract

Disclosed is a process for the production of lower olefins by the conversion of a feed stream comprising carbon monoxide and hydrogen, and catalysts as used therein, such as a Fischer-Tropsch process. By virtue of the invention, lower olefins can be formed from synthesis gas, with high selectivity, and low production of methane. The catalysts used herein comprise an α-alumina support, and a catalytically active component that comprises iron-containing particles dispersed onto the support in at least 1 wt. %. The majority of the iron-containing particles is in direct contact with the α-alumina and is well-distributed thereon. Preferably, the iron-containing particles have an average particle size below 30 nm, and most preferably below 10 nm. The supported catalysts not only show a high selectivity, but also a high catalyst activity and chemical and mechanical stability.


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