The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Mar. 10, 2015

Filed:

Dec. 17, 2009
Applicants:

Veli-matti Purola, Hamari, FI;

Anja Mannerla, Espoo, FI;

Inventors:

Veli-Matti Purola, Hamari, FI;

Anja Mannerla, Espoo, FI;

Assignee:

Borealis AG, Vienna, AT;

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C07C 409/10 (2006.01); C07C 407/00 (2006.01);
U.S. Cl.
CPC ...
C07C 409/10 (2013.01); C07C 407/00 (2013.01); C07C 407/003 (2013.01);
Abstract

A process for oxidizing cumene to cumene hydroperoxide using an oxygen containing gas, which process composes—conducting a cumene feed and an oxygen containing gas feed to at least the first oxidation reactor in a series of 3-8 reactors, thereby forming an oxidation mixture, and—conducting the oxidation mixture from one oxidation reactor to at least one subsequent reactor, wherein—the reactors are operated with reducing liquid levels; —the oxidation is operated as a dry oxidation, whereby the only gaseous feeds conducted to the oxidation reactors are the cumene feed and the oxygen containing gas feed; —the oxygen containing gas feed is washed with caustic and then with water to remove all acidic or caustic traces before conducting it into an oxidation reactor; —the pressure within each oxidation reactor is in the range of 0-10 barg; —the off-gases from the top section of each oxidation reactor are separated and cooled, whereby a condensate containing unreacted cumene is formed, and—washing the condensate and recycling at least a part of it to at least the first oxidation reactor; —the non-condensed off-gases are treated in a thermal oxidizer; and—the first reactor in the series of oxidation reactors has a liquid inventory of 30-300% larger than in the remaining reactors, preferably 50-100%, or the first two reactors in the series of oxidation reactors have a liquid inventory of 30-300% larger than in the remaining reactors, preferably 50-100%.


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