The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Mar. 10, 2015

Filed:

May. 19, 2010
Applicants:

Claude Mercier, Shanghai, CN;

Floryan DE Campo, Shanghai, CN;

Sébastien Righini, Lyons, FR;

Inventors:

Claude Mercier, Shanghai, CN;

Floryan De Campo, Shanghai, CN;

Sébastien Righini, Lyons, FR;

Assignees:

Rhodia Operations, Paris, FR;

Solvay (China) Co., Ltd., Shanghai, CN;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 309/75 (2006.01); C07C 41/01 (2006.01); C07C 303/28 (2006.01); C07C 41/26 (2006.01); C07C 303/30 (2006.01);
U.S. Cl.
CPC ...
C07C 303/28 (2013.01); C07C 41/26 (2013.01); C07C 303/30 (2013.01);
Abstract

A process for preparing a 5-halophenol, ortho-substituted by an electron-donating group, is described. Also described, is a process for preparing a sulphonic ester of an ortho-substituted phenol, which is the synthesis intermediate for the ortho-substituted 5-halophenol. The process for preparing a phenol ortho-substituted by an electron-donating group and protected in the form of a sulphonic ester can include reacting a phenol ortho-substituted by an electron-donating group with a sulphonylating agent in the presence of a Lewis acid. The process for preparing a 5-halophenol ortho-substituted by an electron-donating group can include a first step of preparing a phenol ortho-substituted by an electron-donating group and protected in the form of a sulphonic ester, as described above; a second step of halogenating the protected phenol intermediate obtained in the preceding step, in the position para to the electron-donating group; and a third step of deprotecting the sulphonic ester function to hydroxyl.


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