The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Mar. 10, 2015

Filed:

Mar. 16, 2005
Applicants:

Junrong Zheng, Stanford, CA (US);

Rahmi Ozisik, Niskayuna, NY (US);

Richard W. Siegel, Menands, NY (US);

Inventors:

Junrong Zheng, Stanford, CA (US);

Rahmi Ozisik, Niskayuna, NY (US);

Richard W. Siegel, Menands, NY (US);

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
B32B 15/08 (2006.01); B82Y 30/00 (2011.01); C08K 3/22 (2006.01);
U.S. Cl.
CPC ...
B82Y 30/00 (2013.01); C08K 3/22 (2013.01); C08K 2003/2296 (2013.01); C08K 2201/011 (2013.01);
Abstract

PU/ZnO nanocomposites are provided wherein the addition of less than 1 vol % 33 nm ZnO nanoparticles into a PU matrix effect a decrease in the Young's Modulus and storage modulus of the polymer, while simultaneously effecting an increase glass transition temperature of the polymer. Detailed experiments are described (e.g., FTIR, DMTA, FESEM and AFM) that suggest that the reaction between hydroxyl groups of the ZnO nanoparticles and isocyanate groups of the polyurethane prepolymer disrupts the self-assembly of the phase separation in PU. Phase separation is responsible for the good mechanical properties of PU. Further, detailed experiments suggest that the increase of the glass transition temperature results from the crosslinking effect of the ZnO nanoparticles.


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