The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Mar. 10, 2015

Filed:

Mar. 14, 2013
Applicant:

Ohio Aerospace Institute, Brook Park, OH (US);

Inventors:

Mary Ann B. Meador, Strongsville, OH (US);

Baochau N. Nguyen, North Royalton, OH (US);

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C08G 63/00 (2006.01); C08G 18/38 (2006.01); C08G 18/18 (2006.01); C08G 65/38 (2006.01); B32B 7/02 (2006.01); D02G 3/00 (2006.01); C08G 73/10 (2006.01); C08J 9/00 (2006.01); C08G 18/64 (2006.01); C08J 9/28 (2006.01);
U.S. Cl.
CPC ...
C08G 73/1046 (2013.01); C08J 9/00 (2013.01); C08G 18/6438 (2013.01); C08J 9/28 (2013.01); C08G 73/1035 (2013.01); C08J 2201/026 (2013.01); C08J 2201/0542 (2013.01); C08J 2203/06 (2013.01); C08J 2203/08 (2013.01); C08J 2205/026 (2013.01); C08J 2379/02 (2013.01);
Abstract

Porous cross-linked polyimide-urea networks are provided. The networks comprise a subunit comprising two anhydride end-capped polyamic acid oligomers in direct connection via a urea linkage. The oligomers (a) each comprise a repeating unit of a dianhydride and a diamine and a terminal anhydride group and (b) are formulated with 2 to 15 of the repeating units. The subunit was formed by reaction of the diamine and a diisocyanate to form a diamine-urea linkage-diamine group, followed by reaction of the diamine-urea linkage-diamine group with the dianhydride and the diamine to form the subunit. The subunit has been cross-linked via a cross-linking agent, comprising three or more amine groups, at a balanced stoichiometry of the amine groups to the terminal anhydride groups. The subunit has been chemically imidized to yield the porous cross-linked polyimide-urea network. Also provided are wet gels, aerogels, and thin films comprising the networks, and methods of making the networks.


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