The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Mar. 03, 2015

Filed:

Oct. 29, 2013
Applicant:

Evonik Degussa Gmbh, Essen, DE;

Inventors:

Herbert Plenio, Bensheim, DE;

Christoph Fleckenstein, Freigericht-Somborn, DE;

Renat Kadyrov, Frankfurt, DE;

Juan Almena, Hanau, DE;

Axel Monsees, Frankfurt, DE;

Thomas Riermeier, Ober-Ramstadt, DE;

Assignee:

Evonik Degussa GmbH, Essen, DE;

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C07F 9/02 (2006.01); C07C 2/88 (2006.01); B01J 31/24 (2006.01); C07F 9/50 (2006.01); C07F 9/54 (2006.01); C07C 17/26 (2006.01); C07C 41/30 (2006.01); C07C 45/62 (2006.01); C07C 201/12 (2006.01); C07C 209/68 (2006.01); C07C 253/30 (2006.01); C07D 213/16 (2006.01); C07D 213/22 (2006.01); C07D 213/73 (2006.01); C07D 265/30 (2006.01);
U.S. Cl.
CPC ...
C07C 2/88 (2013.01); B01J 31/2404 (2013.01); B01J 31/2447 (2013.01); C07F 9/5022 (2013.01); C07F 9/5442 (2013.01); C07C 17/26 (2013.01); C07C 41/30 (2013.01); C07C 45/62 (2013.01); C07C 201/12 (2013.01); C07C 209/68 (2013.01); C07C 253/30 (2013.01); C07D 213/16 (2013.01); C07D 213/22 (2013.01); C07D 213/73 (2013.01); C07D 265/30 (2013.01); B01J 2231/321 (2013.01); B01J 2231/4227 (2013.01); B01J 2231/4266 (2013.01); B01J 2231/4283 (2013.01); B01J 2531/824 (2013.01);
Abstract

The invention is directed to a phosphine compound represented by general formula (1) wherein R' and R″ independently are selected from alkyl, cycloalkyl and 2-furyl radicals, or R′ and R″ are joined together to form with the phosphorous atom a carbon-phosphorous monocycle comprising at least 3 carbon atoms or a carbon-phosphorous bicycle; the alkyl radicals, cycloalkyl radicals, and carbon-phosphorous monocycle being unsubstituted or substituted by at least one radical selected from the group of alkyl, cycloalkyl, aryl, alkoxy, and aryloxy radicals; Cpis a partially substituted or completely substituted cyclopentadien-1-yl group, including substitutions resulting in a fused ring system, and wherein a substitution at the 1-position of the cyclopentadien-1-yl group is mandatory when the cyclopentadien-1-yl group is not part of a fused ring system or is part of an indenyl group. Also claimed is the use of these phosphines as ligands in catalytic reactions and the preparation of these phosphines.


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