The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Feb. 24, 2015

Filed:

Apr. 16, 2012
Applicants:

Wanbin Zhang, Shanghai, CN;

Delong Liu, Shanghai, CN;

Hui Guo, Shanghai, CN;

Yangang Liu, Shanghai, CN;

Inventors:

Wanbin Zhang, Shanghai, CN;

Delong Liu, Shanghai, CN;

Hui Guo, Shanghai, CN;

Yangang Liu, Shanghai, CN;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07F 15/00 (2006.01); C07C 29/145 (2006.01); C07C 37/00 (2006.01); C07C 41/26 (2006.01); C07C 213/00 (2006.01); C07B 53/00 (2006.01);
U.S. Cl.
CPC ...
C07C 29/145 (2013.01); C07C 37/002 (2013.01); C07C 41/26 (2013.01); C07C 213/00 (2013.01); C07B 53/00 (2013.01); C07B 2200/07 (2013.01); C07C 2102/08 (2013.01); C07C 2102/10 (2013.01);
Abstract

The invention relates to an asymmetric hydrogenation method for ketone compounds, comprising the step of: under hydrogen atmosphere, in the presence of an in situ catalyst derived from a chiral ligand and a ruthenium salt, adding a ketone compound and a base into a second solvent to carry out an asymmetric hydrogenation for the ketone compound. The invention can obtain a conversion of 100% and a highest asymmetric inducement effect of 99.7% for the ketone compound. The invention has the advantages including simple procedure, high conversion and selectivity, good atom economy and good prospect of industrial application.


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