The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Feb. 17, 2015

Filed:

Oct. 04, 2013
Applicants:

Max Braun, Wedemark, DE;

Stefan Palsherm, Barsinghause, DE;

Uta Claassen, Hohenhameln, DE;

Alain Lambert, Beauvechain, BE;

Inventors:

Max Braun, Wedemark, DE;

Stefan Palsherm, Barsinghause, DE;

Uta Claassen, Hohenhameln, DE;

Alain Lambert, Beauvechain, BE;

Assignee:

Solvay SA, Brussels, BE;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 45/41 (2006.01); C07D 211/02 (2006.01); C07D 213/64 (2006.01); C07D 401/00 (2006.01); C07C 45/65 (2006.01);
U.S. Cl.
CPC ...
C07C 45/41 (2013.01); C07C 45/65 (2013.01);
Abstract

Process for synthesizing a chemical, in particular an agriculturally or pharmaceutically active compound, including: a first step comprising reacting a carboxylic acid halide with a vinyl ether to prepare a halogenated precursor of an alkenone; a second step comprising eliminating hydrogen halide from such precursor to form an alkenone, preferably by thermolysis under specific conditions; and a third step which uses the formed alkenone as a building block to synthesize the chemical. First step may be done in a liquid reaction medium comprising an alkenone or a halogenated alkenone precursor, or in a liquid reaction medium in turbulent state, specifically by creation of gas bubbles of the carboxylic acid halide herein. Second step may include a flash thermolysis, vacuum thermolysis, thermolysis under stripping with inert gas, and/or a thermolysis at a temperature from >90° C. to 120° C. Third step preferably comprises reacting the alkenone with a nitrogen-containing compound.


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