The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Feb. 17, 2015

Filed:

Oct. 25, 2012
Applicant:

Shell Oil Company, Houston, TX (US);

Inventors:

Justus Theodorus Gerardus Te Braake, Amsterdam, NL;

Maarten Bracht, Amsterdam, NL;

Desmond Andrew Bungku, Amsterdam, NL;

Wouter David Van De Graaf, Amsterdam, NL;

Xander Linders, Amsterdam, NL;

Sivakumar Sadasivan Vijayakumari, Amsterdam, NL;

Assignee:

Shell Oil Company, Houston, TX (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
B01D 53/047 (2006.01); B01D 53/04 (2006.01); C10K 1/32 (2006.01); C10G 2/00 (2006.01); B01D 53/22 (2006.01);
U.S. Cl.
CPC ...
B01D 53/04 (2013.01); B01D 53/047 (2013.01); C10K 1/32 (2013.01); C10G 2/32 (2013.01); B01D 53/229 (2013.01); B01D 2253/102 (2013.01); B01D 2253/104 (2013.01); B01D 2253/108 (2013.01); B01D 2253/116 (2013.01); B01D 2256/10 (2013.01); B01D 2256/16 (2013.01); B01D 2257/502 (2013.01); B01D 2259/40001 (2013.01); B01D 2259/40007 (2013.01); B01D 2259/4062 (2013.01); B01D 2259/414 (2013.01); C10G 2300/1022 (2013.01); C10G 2300/4081 (2013.01);
Abstract

A method for producing a gas comprising at least 80 vol % carbon monoxide from a Fischer-Tropsch off-gas comprises: (1) feeding Fischer-Tropsch off-gas through a column comprising an adsorbent bed at high pressure and discharging effluent; (2) reducing the pressure in the column and the bed slightly; (3) rinsing the column and the adsorbent bed with methane or a mixture of methane and carbon dioxide; (4) reducing the pressure of the column and adsorbent bed to a low pressure; (5) rinsing the column and adsorbent bed with a mixture of hydrogen and nitrogen; (6) pressurizing the column and adsorbent bed to a high pressure using a mixture of hydrogen and nitrogen. The product stream obtained in step (3) comprising at least 80 vol % carbon monoxide can be sent as feed to a Fischer-Tropsch reaction. In an embodiment, a gas comprising at least 80 vol % hydrogen is also produced.


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