The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Feb. 10, 2015

Filed:

Jun. 03, 2011
Applicants:

Ali Harlin, Espoo, FI;

Jari Räsänen, Imatra, FI;

Tapani Penttinen, Huutjärvi, FI;

Inventors:

Ali Harlin, Espoo, FI;

Jari Räsänen, Imatra, FI;

Tapani Penttinen, Huutjärvi, FI;

Assignee:

Stora Enso OYJ, Helsinki, FI;

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C07C 51/16 (2006.01); C07C 51/255 (2006.01); C07C 51/265 (2006.01); C10G 3/00 (2006.01); C07C 1/207 (2006.01);
U.S. Cl.
CPC ...
C10G 3/50 (2013.01); C07C 51/265 (2013.01); C10G 3/49 (2013.01); C07C 1/2078 (2013.01); C07C 51/16 (2013.01); C07C 2521/04 (2013.01); C07C 2523/883 (2013.01); C10G 3/46 (2013.01); C10G 2400/30 (2013.01); C10G 2300/1014 (2013.01);
Abstract

A method of manufacturing aromatic hydrocarbons, which are suitable for the production of terephthalic acid, from tall oil-based raw material. According to the invention, the raw material that contains tall oil or its fraction is catalytically deoxygenated with hydrogen, and one or more aromatic hydrocarbons that can be converted into terephthalic acid are separated from the deoxygenated reaction yield. The deoxygenation catalyst is a NiMo catalyst and, in addition, a cracking catalyst can be used, such as an acidic zeolite catalyst. The separated hydrocarbon can be p-xylene, o-xylene or p-cymene. According to the invention, these can be converted by oxidation and, when needed, by a re-arrangement reaction into terephthalic acid that is suitable for the source material of the manufacture of bio-based polyethylene terephthalate.


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