The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jan. 27, 2015

Filed:

Dec. 12, 2008
Applicants:

Ulrich Wiesner, Ithaca, NY (US);

Mahendra Christopher Orilall, Vancouver, CA;

Jinwoo Lee, Kyungbuk, KR;

Francis J. Disalvo, Jr., Ithaca, NY (US);

Inventors:

Ulrich Wiesner, Ithaca, NY (US);

Mahendra Christopher Orilall, Vancouver, CA;

Jinwoo Lee, Kyungbuk, KR;

Francis J. DiSalvo, Jr., Ithaca, NY (US);

Assignee:

Cornell University, Ithaca, NY (US);

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
B28B 1/14 (2006.01); C01G 23/053 (2006.01); C01B 13/18 (2006.01); C01G 1/02 (2006.01); C01G 23/047 (2006.01); C01G 33/00 (2006.01); C04B 35/45 (2006.01); C04B 38/06 (2006.01); C04B 111/00 (2006.01);
U.S. Cl.
CPC ...
C01G 23/0536 (2013.01); C01B 13/18 (2013.01); C01G 1/02 (2013.01); C01G 23/047 (2013.01); C01G 23/053 (2013.01); C01G 33/00 (2013.01); C04B 35/45 (2013.01); C04B 38/062 (2013.01); C01P 2002/88 (2013.01); C01P 2004/04 (2013.01); C01P 2006/12 (2013.01); C01P 2006/14 (2013.01); C01P 2006/17 (2013.01); C01P 2006/40 (2013.01); C04B 2111/0081 (2013.01);
Abstract

Highly crystalline metal oxide-carbon composites, as precursors to thermally stable mesoporous metal oxides, are coated with a layer of amorphous carbon. Using a 'one-pot' method, highly crystalline metal oxide-carbon composites are converted to thermally stable mesoporous metal oxides, having highly crystalline mesopore walls, without causing the concomitant collapse of the mesostructure. The 'one-pot' method uses block copolymers with an sp or sp 2 hybridized carbon containing hydrophobic block as structure directing agents which converts to a sturdy, amorphous carbon material under appropriate heating conditions, providing an in-situ rigid support which maintains the pores of the oxides intact while crystallizing at temperatures as high as 1000 deg C. A highly crystalline metal oxide-carbon composite can be heated to produce a thermally stable mesoporous metal oxide consisting of a single polymorph.


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