The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jan. 06, 2015

Filed:

Mar. 27, 2012
Applicants:

Scott Donald Barnicki, Kingsport, TN (US);

Robert Thomas Hembre, Johnson City, TN (US);

Stephen Neal Falling, Kingsport, TN (US);

Inventors:

Scott Donald Barnicki, Kingsport, TN (US);

Robert Thomas Hembre, Johnson City, TN (US);

Stephen Neal Falling, Kingsport, TN (US);

Assignee:

Eastman Chemical Company, Kingsport, TN (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 51/12 (2006.01); C07C 59/06 (2006.01);
U.S. Cl.
CPC ...
C07C 51/12 (2013.01); C07C 51/12 (2013.01); C07C 59/06 (2013.01);
Abstract

Disclosed is a process for the production and purification of glycolic acid or glycolic acid derivatives by the carbonylation of methylene dipropionate in the presence of a homogeneous acid catalyst and propionic acid. This invention discloses hydrocarboxylations and corresponding homogeneous acid catalyst and glycolic acid separations. The homogeneous acid catalyst is readily separated from the hydrocarboxylation reaction effluent and recycled and the propionic acid is readily removed from the glycolic acid and the propionic acid is recycled.


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