The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Dec. 30, 2014

Filed:

Apr. 11, 2007
Applicants:

James E. Torres, Baton Rouge, LA (US);

Alvin E. Harkins, Jr., Baton Rouge, LA (US);

Thanikavelu Manimaran, Baton Rouge, LA (US);

B. Gary Mckinnie, Magnolia, AR (US);

Inventors:

James E. Torres, Baton Rouge, LA (US);

Alvin E. Harkins, Jr., Baton Rouge, LA (US);

Thanikavelu Manimaran, Baton Rouge, LA (US);

B. Gary McKinnie, Magnolia, AR (US);

Assignee:

Albemarle Corporation, Richmond, VA (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 21/00 (2006.01); C07C 17/08 (2006.01);
U.S. Cl.
CPC ...
C07C 17/08 (2013.01); C07C 17/08 (2013.01); C07C 19/075 (2013.01);
Abstract

A process for the production of an aliphatic bromide in which the bromine atom is attached to a terminal carbon atom, which process comprises continuously feeding olefin having a terminal double bond, gaseous hydrogen bromide, and a molecular oxygen-containing gas into a liquid phase reaction medium comprised of aliphatic bromide to cause anti-Markovnikov addition of HBr to terminal olefin, the feeds being proportioned and maintained to provide a molar excess of hydrogen bromide relative to terminal olefin in the range of about 1 to about 5 percent, and a molar ratio of molecular oxygen to terminal olefin of less than 0.005. The process is especially suited for production of n-propyl bromide.


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